A new computer would be necessary for the 64-bit only CS6 - and worth it to edit the much larger HD format as easily as you did with DV footage. Adobe has recommendations on computer components, and a great website that tests editing computers is :
http://www.videoguys.com/Guide/C/DIY%2bSystems.aspx
As for the learning curve... well there will be one of course. Single track editing does differ from 2-track. But after a few projects you'll begin to discover a work flow. There are lots of tutorials to be found online using PPro.