Jake -
This is not advice you're asking for, this is a complete education in a field which is very complex. I suggest you start at:
http://www.neilblevins.com/cg_education/cg_education.htm
Playing around will only get you so far in a discipline in which randomly fiddling with settings often gets you nothing, or in deep trouble. I would suggest getting started with the tutorials of the 3D software you have, going through the Neil Blevins site, and then coming back with specific questions. It's going to be fun, daunting, and frustrating at times. Good luck!
Joe Bourke
Owner/Creative Director
Bourke Media
http://www.bourkemedia.com